Preformed Thermoplastic Pavement Marking and Method Utilizing Large Aggregate for Improved Skid Resistance and Reduced Tire Tracking

ABSTRACT

The present disclosure describes a preformed or in some cases a hot applied thermoplastic marking composition comprising a planar top surface portion and a planar bottom surface portion that are coplanar to each other, wherein said bottom surface portion is directly applied to a substrate via application of heat or pressure or both heat and pressure and wherein said top surface portion comprises an intermix that exits throughout said thermoplastic composition and includes large grit size aggregate in the range of about 8 to about 20 mesh or grit size, thereby reducing or eliminating tire tracking while also improving long-term skid resistance.

PRIORITY

The present application is a divisional of and claims priority under 35U.S.C. § 120 from U.S. patent application Ser. No. 12/592,458 entitled,“Preformed Thermoplastic Pavement Marking and Method Utilizing LargeAggregate for Improved Long Term Skid Resistance and Reduced TireTracking”, filed 25 Nov. 2009, which is a Continuation-in-Part of andclaims priority under 35 U.S.C. § 120 from U.S. patent application Ser.No. 10/816,635 filed Apr. 2, 2004 and entitled, “Pavement MarkingPattern and Method”, granted on Jan. 12, 2010 as U.S. Pat. No.7,645,503.

FIELD OF THE INVENTION

The invention herein pertains to thermoplastic pavement markingmaterials comprising large grit size aggregate to improve long-term skidresistance and reduce tire tracking, and particularly pertains to suchmarkers as lines, legends, arrows, indicia, and decorative markingincluding pavement marking patterns utilizing thermoplastic sheetingwhich utilize an adhesive (sprayable or otherwise) to maintain theintegrity of the pattern prior to its application to a substrate.

BACKGROUND OF THE INVENTION

Traffic markings convey information to drivers and pedestrians byproviding exposed visible, reflective, colored and/or tactile surfacesthat serve as indicia. In the past, such a function was typicallyaccomplished by painting a traffic surface. Modern marking materialsoffer significant advantages over paint such as dramatically increasedvisibility and/or reflectance, improved durability, and temporaryremovable marking options. Examples of modern pavement marking materialsare thermoplastic, pavement marking sheet materials, tapes and raisedpavement markers.

Preformed and hot applied thermoplastic materials used as pavementmarkings or for other indicia possess many advantages compared to paintsand other less durable markings. These materials can be used for years.Known materials using high friction aggregates on the surface to improvefriction has been known. The surface applied aggregates provide goodinitial values, however as the surface is worn due to traffic, the skidresistance decreases. After surface layers containing anti-skidmaterials become worn out these aggregate materials loose theireffectiveness and become slippery because they do not contain highfriction particles (of sufficient size to provide good skid properties).

Current thermoplastics include small particulate aggregate to improvethe skid-resistant properties of the markers. However, over time, it hasbeen shown that when such particulates are too small, they become worntoo quickly and thus do not provide sufficient skid-resistance for hightraffic areas. Today's thermoplastic materials do not include propertiesof long-term skid resistance and reduced tire tracking. In additiontoday's preformed thermoplastic decorative patterned materials do notinclude both the properties of facilitated assembly via an adhesivespray and long-term skid resistance and reduced tire tracking.

A review of these issues demonstrates the need for thermoplasticproducts that both reduces tire tracking and improves long term skidresistance once the marking product has been installed on the roadsurface and also ensures that the integrity of the product (and patternif so desired) is maintained during handling and installation.

DESCRIPTION OF RELEVANT ART

U.S. Pat. No. 3,958,891 to Eigenmann, Ludwig, and not assigned,describes an aggregate for securing in a layer of material which is usedto form a traffic-regulating indicium, so as to improve the nighttimevisibility characteristics and anti-skid characteristics of thetraffic-regulating indicium. The aggregate comprises a core bodysurrounded at least partially by a mass of shock-absorbent bindersubstance and a plurality of elements that improve either nighttimevisibility or anti-skid properties, or both. The elements are arrangedin and bound by the binder substance such that the latter substantiallyfills the interspaces between at least the majority of adjacent pairs ofthe aforementioned elements, some of which being arranged adjacent to anexternal surface of the mass so as to impart a roughened texture to theexternal surface, thereby permitting the aggregate to be firmly securedin the traffic-regulating indicium. The remainder of the elements aredistributed among different levels interiorly of the mass so thatprogressive wear of the aggregate and concomitant detachment of elementsfrom the aggregate causes exposure of others of the elements, therebyconveying long-term durability to the traffic-regulating indicium.

U.S. Pat. No. 4,020,211 to Eigermann, Luwig and not assigned describes anew material adapted to be laid down and adhesively secured on a roadsurface to provide a traffic regulating sign with the material which hasan upper surface exposed to traffic and provided with a plurality ofsharp tips projecting above the surface for imparting good non-skidproperties thereto, the new material comprising an upper layer adjacentto the upper surface, at least partially embedding hard particles toform sharp tips and consists of a polymeric resin having a highmolecular cohesion such as a polyamide resin, a polyurethane resin or apolyterephthalic resin, thereby adding improved wear resistanceproperties to non-skid and high visibility properties.

U.S. Pat. No. 4,937,124 to Pafilis, Michail and not assigned, describesa nonskid element as an antislipping means on a carpet-like floorcovering. The nonskid element is a web that includes a plain bottomwall, and the bottom wall includes a covering with band-like holdingpins.

U.S. Pat. No. 5,077,117 to Harper, et. al., describes a pavement markingmaterial comprising a flexible base sheet that is conformable to anirregular pavement surface. A durable, wear-resistant, polymeric toplayer is adhered to one surface of the base sheet. The top layer iscapable of undergoing brittle fracture at a temperature from 0 degreesCentigrade to 45 degrees Centigrade such that when the base sheetconforms to an irregular surface the top layer readily forms ruptures torelieve stress build-up in the top layer as the regions of the top layerdefined by the ruptures remain adhered to and follow the conformance ofthe base sheet. A plurality of particles are embedded in and protrudefrom the top layer. The particles comprise retroreflective beads andskid-resistant granules. In a preferred embodiment, the top layer ischaracterized by a Young's modulus of from about 50,000 psi to about300,000 psi, and a percent elongation at break of from about 4% to about35%.

U.S. Pat. No. 6,217,252 to Tolliver, Howard R, et. al., and assigned to3M, describes a method for marking a transportation surface in which thesurface is heated to a temperature above the ambient temperature and afinely-divided, free flowing, flame-sprayable, powder binder materialselected from the group consisting of acrylic polymers and copolymers,olefin polymers and copolymers having a number average molecular weightgreater than 10,000, urethane polymers and copolymers, curable epoxyresins, ester polymers and copolymers, and blends thereof is melted orsubstantially softened. The molten or softened binder is then applied tothe surface with a particulate topcoat or particulate filler selectedfrom the group consisting of reflective elements; skid-resistantparticles, magnetizable particles and mixtures thereof, and finally theapplied materials are allowed to cool to form a marker in which thebinder adheres directly to the surface.

U.S. Pat. No. 3,935,365 to Eigenmann, Ludwig, and not assigned,describes a tape material for securement to primer layers provided onroadway pavements so as to form traffic-regulating indicia on thelatter. The tape material comprises a first layer that contains apolymeric binder having high molecular cohesion and one surface adaptedto face towards a roadway pavement and another surface adapted to beexposed to traffic, a plurality of hard particles having a minimum ofabout 6 on the Mohs' Hardness Scale, some of which should have a sharptip, distributed among various levels of the aforementioned first layer,and a second layer adapted to be secured to a primer layer on theroadway pavement bonded to one surface of the first layer. The secondlayer is compatible with the first layer so that a firm bond is formedbetween them. It is also compatible with the primer layer so that a bondforms between them when the tape material is placed on the primer layer.This tape material imparts good anti-ski properties to atraffic-regulating indicium formed therewith due to the presence of thetips of the hard particles, which provide gripping areas when exposed.It is also an effective skid-resister during wear of thetraffic-regulating indicium due to the distribution of the hardparticles among various levels of the first layer, which enables freshhard particles to become exposed as hard particles next to the latterare removed by wear.

U.S. Pat. No. 5,053,253 to Haenggi, Robert, et. al., and assigned toMinnesota Mining and Manufacturing Company, describes a method ofproducing skid-resistant substrate marking sheet in which a base sheetis provided and an upward face of the base sheet is coated with a liquidbonding material. A plurality of ceramic skid-resistant spheroids isembedded in the liquid bonding material, wherein the ceramic spheroidsare characterized by having rounded surfaces and no substantial pointsand characterized by Krumbein roundness of at least 0.8. The liquidbonding material is then cured to a solid adherent polymeric matrixcoating with the ceramic skid-resistant spheroids partially embedded,wherein the spheroids comprise a fired ceramic made from various rawmaterials.

U.S. Pat. No. 5,094,902 to Haenggi, Robert, et. al., and assigned toMinnesota Mining and Manufacturing Company, describes a skid-resistant,surface marking material, comprising a polymer matrix phase having a topsurface and a plurality of opaque, skid-resistant ceramic spheroidspartially embedded in and protruding from the top surface of the polymermatrix phase, wherein said ceramic spheroids have rounded surfaces andno substantial points, and wherein said ceramic spheroids have aKrumbein roundness of at least 0.8.

U.S. Pat. No. 6,679,650 to Britt, Jerry, et. al., and assigned to EnnisPaint Incorporated, describes a marked pavement system comprising apavement surface, a first marking stripe adhered to the top of thepavement surface with a thickness of at least about 40 mils to about 110mils and comprised of a solidified thermoplastic resin composition witha black pigment, and a second marking stripe adhered to the surface ofthe first marking stripe with a thickness of at least 40 mils to 750mils. The second marking stripe should be narrower than the firstmarking stripe and comprised of a solidified thermoplastic resincomposition with a pigment that visibly contrasts with the first markingstripe, wherein the marked pavement system is highly visible during thedaylight hours and during periods of rain.

U.S. Pat. No. 5,536,569 to Lasch, James E., et. al., and assigned toMinnesota Mining and Manufacturing Company, describes a conformablepavement marking with a top surface useful as a marking indicium and abottom surface, the marking sheet comprising a conformance layer with athickness of 75 to 1250 micrometers of a composite material. Thecomposite material should include 50 to 85 volume percent of a ductilethermoplastic polymer selected from the group consisting ofpolyethylene, polypropylene, polybutylene, ethylene copolymers,polyvinylidene fluoride, polytetrafluoroethylene, polyvinyl polymers,polyamides, and polyurethanes, and 15 to 50 volume percent mineralparticulate with a mean particle size of at least 1 micrometer. Theconformance layer requires, when tested at 25 degrees Celsius using astandard tensile strength apparatus, not more than 35 Newtons force percentimeter of width to deform a sample to 115% of the original samplelength when tested at a strain rate of 0.05 sec-1. The top layer isdistinct from the conformance layer, 80-250 micrometers thick, and ismade of a thermoplastic polyolefin.

U.S. Pat. No. 6,790,880 to Purgett, Mark, et. al., and assigned to 3M,describes a pavement marking comprising a binder having polyurea groups,wherein the binder is prepared from a coating composition comprising oneor more aliphatic secondary amines, one or more polylsocynanates, and atleast about 15 weight percent non-soluble material based on the weightof the final dried coating, and reflective elements. The patent alsodiscloses the pavement marking wherein the binder is a sprayable,two-part coating composition.

U.S. Pat. No. 6,116,814 to Dietrichson, Stein, and assigned to Rieber &Son, Division Nor-Skilt, describes a method for applying markings orsigns on a surface in which a primer layer comprising an uncured plasticmaterial with two or more components is applied to the surface, a heatedmass comprised of a thermoplastic material is laid down on the primerlayer, and the curing of the primer layer is initiated by the heat ofthe aforementioned heated mass.

U.S. Pat. No. 3,664,242 to Harrington, Thomas, et. al., and assigned toMinnesota Mining and Manufacturing Company, describes a method forforming a marking on a roadway that is ready to bear wheeled roadtraffic within seconds after application. First, the surface of theroadway is momentarily heated to a temperature between 150 and 500degrees Fahrenheit. Next, the thus-heated roadway is projected toward amarking material that comprises a continuous stream of solid particlesthat are capable of passing a screen of about 20 mesh with at leastabout 80 weight percent being retained on a screen of about 200 mesh,are non-tacky, non-blocking, free-flowing, and solid at temperatures upto about 120 degrees Fahrenheit, and include a coloring agent in anamount sufficient to color a marking formed from the marking materialand an organic thermoplastic phase that accounts on the average for atleast about 25 volume percent of the marking material and principallycomprises a polyamide condensation product of polycarboxylic acid andpolyamine. Finally, the individual particles are heated as the proceedtoward the roadway to a temperature above 150 degrees Fahrenheitsufficient to at least soften a major portion of the organicthermoplastic phase of the particles before they reach the pavement, theheated condition of the roadway and the particles being such that theparticles wet and bond rapidly to the surface of the pavement andcoalesce into a film, which subsequently becomes solid, non-tacky, andcapable of bearing wheeled road traffic without tracking.

Great Britain Patent Application No. GB 2429978A to Aubree, Barry Mark,and assigned to Barry Mark Aubree, describes a method of producing athermoplastic road-marking composition that comprises mixing an opaquepigment, a translucent particulate thermoplastic material and reflectiveglass beads such that when the thermoplastic material is subsequentlymelted to bind the composition and the composition is laid as a marking,the glass beads on the visible surface of the markings are notsubstantially obscured by the opaque pigment. The application alsopresents a thermoplastic road-marking composition comprising a mixtureof a particulate filler material, a pigment, a translucent thermoplasticmaterial and reflective glass beads wherein the pigment clings to thefiller material and the reflective glass beads are generally clear ofthe pigment. Accordingly, the thermoplastic road-marking immediately hasretroreflectivity without the requirement for an additional operation ofadding glass beads to the surface of the marking and without the need tolet the road-marking wear before it becomes retroreflective.

WIPO Patent Application No. WO03064771A1 to Hong, Le Hoa, et. al., andassigned to Avery Dennison Corporation, describes a method for securinga preformed pavement marking construction with a top surface and atleast one perimeter edge to pavement with a relatively flat roadwaysurface. The method includes adhering the preformed pavement markingconstruction the roadway surface, providing a curable structuraladhesive, and applying the curable structural adhesive to the at leastone perimeter edge such that the curable structural adhesive overlaps aportion of the top surface of the preformed pavement markingconstruction at its at least one perimeter edge and a portion of theroadway surface. Finally, the curable structural adhesive is cured toform a traffic-bearing top surface extending between the roadway surfaceand the preformed pavement marking construction.

The disclosed review of the relevant art shows the need for athermoplastic pavement marking method using an adhesive (sprayable orotherwise) that maintains the integrity of the pattern and athermoplastic pavement marking composition that includes large grit sizeaggregate to improve long term skid resistance and reduce tire-tracking.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a diagram of a type of preformed thermoplastic pavementmarker, which is more fully described below.

DETAILED DESCRIPTION OF THE DRAWINGS

FIG. 1 illustrates a typical partial decorative pavement marking pattern(10) for application to concrete, asphalt or other suitable substrates.Marking pattern (10) is a brick and mortar pattern used herein forillustration purposes but as would be understood various otherthermosetting and thermoplastic patterns are commercially available suchas (90) herringbone, cobblestone, pavement slabs, horizontal signage,logos and other designs. Also, while many colors are available for thepavement marking patterns, typically different sections of each patternare of different colors, such as a “light” grid or mortar color and a“darker” brick or insert color. The marking patterns typically consistof two or more sections.

Preferred marking pattern (10) shown for demonstration purposes consistsof two separate thermoplastic sections, first section (11) represents agrid or mortar joint and second section (12) represents a brick orinsert (14) with borders (18) as represented. Sections (11) and (12) aregenerally formed independent of each other due to the differences incolor. Pavement marking pattern (10) is planar and is conventionallyformed from a standard thermoplastic. The top portion (11) of themarking pattern is bordered. Large aggregates (20) are shown throughoutthe marker patterns.

SUMMARY OF THE INVENTION

The present disclosure describes a preformed thermoplastic pavementmarking or hot melt applied material with improved long term skidresistance and reduced tire tracking once the pavement marking has beenadhered to road surfaces or other solid substrates. The need exists toproduce preformed thermoplastic pavement marking materials with improvedskid resistance, especially for use in wet conditions and over long termuse to reduced tire tracking—a real detriment to the usefulness ofthermoplastic pavement markings in locations where they are desirable.The preformed thermoplastic material of the present invention iscomprised of about 20% binder and 80% “intermix”, where the intermixincludes non-organics such as silica, calcium, and other inorganicpigments as well as large high friction aggregate capable of passingthrough sieves sizes of about 4 to about 12 together with somewhatsmaller aggregate that is applied to the surface either prior to, orduring installation. The surface applied anti-skid materials providehigh initial friction properties, while large size aggregate in theintermix provides long term skid resistance and improves initialfriction properties by creating an appropriately textured surface.

To achieve the desired traction and friction properties it should berecognized that there is a difference between slip resistance, whichrelates to traffic traveling over the pavement markers at a slow speedand to pedestrian traffic traveling over the same pavement markersurfaces and related to the static COF (coefficient of friction). Skidresistance relates, however to traffic traveling over the pavementmarkers at high speed, and depends on surface texture. Skid resistanceis more applicable to the type of vehicular traffic.

Common test methods for measuring the effectiveness of these pavementmarkers for slip and skid resistance include BPN (ASTM E303), which isthe most commonly used test methodology but does not reflect performanceat high speeds and does not provide for measuring static COF values.

Instead, the “Locked Wheel Test” which produces “FN” or Friction numberand described by ASTM E274 is used by many states within the UnitedStates and provides a methodology for measuring friction values at highspeeds, simulates real traffic conditions, and requires actual roadinstallation. There are also other test methods for measuring frictionat high speeds. Results from different test methods can be normalized orcombined using the IFI (International Friction Index, ASTM E1960) whichprovides for combining friction and texture indices (F60 and S_(p)).

The required materials for the present invention to achieve both thenecessary slip and skid resistance are those that contain high frictionlarge aggregates in the intermix with a weight percent content of from 5percent to 65 percent. The optimal size of the large aggregates is fromabout 4 to about 16 grit depending on the specific thickness of thethermoplastic sheets that contain the marker patterns—confirm sizes Thepresent invention also includes cases where the thermoplastic roadmarker patterns contain surface applied large aggregate in a range fromabout 14 to about 20 grit Product using small particle aggregate sizes(approximately 24 grit or mesh) covered the surface area of thethermoplastic marking sheets more effectively, however, these aggregatesdid not provide the required skid or tire track resistance.

It has been shown that it is possible to use single grit size aggregatein the intermix. The use of an intermix of different grit sizedaggregates in different proportions based on the need for the future useof different materials (larger sizes for thicker and largerthermoplastic sheets and smaller aggregates for narrow strips) is alsopart of the present disclosure.

The aggregates used primarily exhibit a Mohs hardness of greater than 6,including corundum, quartz, granite, calcined clay, nickel slag, silicondioxide and others (trade names of such materials include Mulcoa grades47, 60 and 70, AlphaStar®, Ultrablast®, and Alodur® which providehardness ratings in the range of 6.5 to 9). A portion of the intermixused with the thermoplastic road marking includes 16 grit size aggregatealso with a hardness in the Mohs scale reading of greater than 6, whichhas never been tried before in preformed or hot melt appliedthermoplastic surface applications, and has resulted in improvedfriction.

An additional desired result is improved overall skid resistance of thepreformed thermoplastic markers without any associated discoloration.The aforestated special aggregates also improve the coefficient ofsliding friction (COF) as determined per the ASTM E274 test. As the COFdecreases below a certain level on the surrounding asphalt, a smallwheel grabs onto the asphalt and if the COF is reduced on the pavementmarking too much, undesirable skidding will occur. It is desirable thatthe COF of the preformed or hot melt thermoplastic match or be greaterthan the road pavement surface. The COF, in this case, as measured perASTM E274 requires using a small cart pulled behind a car with a wheelattached to the bottom of the cart that rides at the speed of the car,thus touching the pavement surface, which eventually results in lockingthe wheel, thereby allowing for measurement of the force of the cart onthe surface.

In this case, the result of using large particle aggregates isanti-intuitive, in that as there is more “gripping” to the thermoplasticmarker surface adhered to the underneath pavement surface, the trafficthat travels over this maker pavement surface with the special aggregateresults in providing less tire tracking and skid marks. Tire tracking ismeasured by the size and number of undesirable resultant markings causedby traffic as well as discoloration of the thermoplastic markingsurface. The reduction in COF does, however, correlate with increasingskid and when the COF increases, this will correlate with decreasingskid.

Therefore, a surprising result found during the course ofexperimentation and resulting in an important embodiment of the presentapplication is that these thermoplastic marking surfaces stay cleanerand possess less tire tracking than marking surfaces without the speciallarge aggregate particles described above.

There is a strong need in the industry to provide a layer of preformedthermoplastic so that these marking surfaces are skid resistant and areused for any crosswalk material. There is also a requirement that theskid resistance (which is quantified by friction number) also providestire tracking reduction.

An additional embodiment and surprising result is that in the past,without the use of these large aggregate materials, the wheel path ortrack is almost always darker in the section of the surface where thevehicle travels over the marking, so that normal free rolling trafficwhich passes over the thermoplastic pavement markers will causedarkening. In the case of the present invention, this is not true andthis undesirable result has been eliminated. The turning traffic, whichcauses more tire shear, also does not cause darker tire tracking.

In the present invention, the use of uniform particulate material orblends of particulate materials for the aggregate with differinghardness values, providing more economical solutions, can be introducedinto the intermix during formulation. The introduction of these blendsusually occurs prior to extrusion and completion of the thermoplasticpavement marking. The aggregates and other particles such as glassbeads, including type 1 and type 3 glass beads, and the inorganicchoices stated above can also, however, be dropped on the hot materialduring installation and completely embedded into body of thethermoplastic marking material in that fashion. The preformedthermoplastic surface marking product can be applied using pressuresensitive adhesives as well as by flame torching.

The resultant properties of the (once applied) thermoplastic markingsurfaces were measured using International Friction Index (IFI)consisting of two parameters:

-   -   F60—calibrated friction at 60 km/h calculated from        DFT20—friction measured at 20 km/h    -   S_(p)—speed constant that depends on surface texture presented        as MPD (mean profile depth, mm).

Materials without large high friction aggregate have an F60 of about0.07 to about 0.10 and an MPD of 0.15 mm to about 0.3 mm. Depending onthe aggregate size used in the present invention, when the intermixbecomes exposed, the F60 increases to between about 0.17 to about 0.4and the MPD to between about 0.50 mm to about 0.75 mm. For comparisonhot mix asphalt has an F60 value of about 0.25 after being exposed totraffic extended lengths of time.

In addition, in recent years increasing numbers of municipalities,office complexes, shopping centers and other commercial developmentshave utilized thermoplastic pavement markings with various patterns anddesigns to guide, decorate, and protect high traffic areas such ashighways, pedestrian crosswalks, parking lots and business entrances.Such patterns may include a first section or grid, for example torepresent the mortar joints in a “brick” design and a plurality ofsecond sections or “bricks” which are coplanar therewith, usually in acolor different from the mortar color. The second section or brickswhich are separately manufactured are inserted into the first section orgrid before application of the pattern to the pavement. Various twosection marking patterns are commonly available such as: herringbone,standard brick, cobblestone, paving slabs and many other designs.Marking patterns with more than two sections are also commonly availablesuch as horizontal highway and street signage, logos and many others.

As hereinbefore mentioned, these marking patterns consist of two or moreindependent sections which must be carefully assembled and handledbefore applying to pavements such as asphalt, concrete or other suitablesubstrates. These marking patterns are placed at desired locations suchas road crosswalks, intersections, parking lots or other sites. In somecases heat is then applied to soften the pavement marking patterncausing it to firmly adhere to the substrate. Various adhesives can alsobe used to adhere the marking pattern to the substrate.

While the purchase of such pavement marking patterns is relativelyinexpensive, much time and labor is devoted to the assembly andapplication of the pattern to the substrate. Most patterns consist oftwo or more sections which are independently formed for manual assemblyat the job site and time and effort is needed to assemble and maintainthe integrity of a pattern before the heat treatment. Usually thepattern placed on the substrate must be moved manually for adjustmentpurposes. During such movement, the independent sections in the patterninadvertently become unaligned, requiring reinsertion or realignment. Ifthe realignment is not precisely accomplished, the marking pattern willhave lost its integrity and the entire pattern must be removed manuallyfrom the substrate, the substrate cleaned and a second attempt at theapplication made with the reinserted or new marking pattern. Thisre-application results in extra time, labor, and materials. In the past,to maintain the integrity of the marking pattern before the heattreatment and during the handling and placement, “spot adhesives” havebeen used which remain somewhat “tacky” after being applied to thebottom of the patterns at the grid intersections to maintain patternintegrity. However, these small adhesive circles or “spots” aregenerally a different type of polymer than the marking pattern and canprevent proper attachment and easy movement of the marking pattern onthe substrate at the spot adhesive locations before and during the heatapplication of the marking. Also, certain spot adhesives are notcompatible with the plastic materials from which the patterns are formedand can cause the pavement marking sections to separate from thesubstrate after the heat application, as only a weak bond is formed withthe substrate.

The major object of the present invention is to provide for long termskid resistance and reduced tire tracking through the addition of largegrit size aggregate. The above stated objectives are realized byproviding a conventional pavement marking pattern formed of athermosetting or thermoplastic which may have two or more sections,manually joined by bridging the bottom surface thereof with an adhesivehaving substantially the same temperature softening point as thesections of the marking pattern. The adhesive can be sprayed primarilyalong the intersections of the pattern to cover a percentage(approximately from 5% to 90%) of the patterned bottom surface areawhile bridging the intersections. The more intricate the pattern (withmore joints or intersections) the greater the percentage of adhesivecoverage required. The spray adhesive can be a typical polyamide, EVAbased hot melt adhesive or other, such as styrene-isoprene-styrenecopolymers, styrene-butadiene-styrene copolymers, ethylene ethylacrylate copolymers, and polyurethane reactive, and preferably consistsof a hot melt polyamide resin based adhesive which is sprayed in acircular or spiral string like configuration at a temperature at orabove its softening point. The sprayed hot adhesive strikes the markingpattern and adheres, bridging and bonding the pattern sections tomaintain pattern integrity during subsequent handling. Uni-Rez 2633 assold by Arizona Chemical Company of P.O. Box 550850, Jacksonville, Fla.32225 is the main ingredient in the preferred hot melt adhesive. Thepreferred hot melt adhesive is formulated with Uni-Rez 2633, estermodified rosins, fillers, extenders, levelers and other conventionalcomponents.

In a typical manufacturing process, various sections of a pavementmarking pattern (e.g. a brick and mortar pattern or any other desiredpattern) are factory assembled and while in assembled form, the bottomof the pattern is sprayed with the hot melt adhesive described aboveusing preferably spray gun model: Hysol-175-spray as manufactured byLoctite Corporation of 1001 Tout Brook Crossing, Rocky hill, Connecticut06067, having various pressures and nozzle settings to select from,depending on the viscosity of the particular adhesive employed. Acircular or spiral string-like adhesive configuration is preferred forthe spray.

Once the sprayed hot melt adhesive has cooled, the grid and inserts aresuitably bridged and joined and the pavement marking pattern is packagedfor shipment. Upon receipt at the job site, the packages are opened andafter the intended substrate, usually asphalt or concrete is properlycleaned and swept, the marking pattern is then placed on the substratewithout concern of disassembly during handling, movement and adjustment.Once suitably placed, a heat application is delivered from aconventional source which softens the marking pattern and the underlyingsprayed adhesive, both of which have the approximate same temperaturesoftening point to thereby affix the pavement marking pattern to thesubstrate. Time and labor are thereby saved as the marking patternsections have been adhered to form a unified pattern by the hot meltadhesive.

As stated above, the present invention includes larger grit sizeaggregate than is normally used in similar preformed thermoplasticpavement marking products. Specifically, the aggregate should be between8 and 12 mesh (grit) in size and may be comprised of quartz, corundum,crushed gravel, crushed granite, or any combination thereof. Theaggregate used may also measure 6 or greater on the Mohs Hardness Scale.This larger grit size improves the skid resistance properties of thepavement marker and also significantly reduces tire tracking incomparison to other similar products, because it ensures that theproduct wears down more slowly, conveying greater durability and alsolonger term skid resistance—often through the end-of-life of the appliedpreformed thermoplastic.

Other advantages achieved using these working examples include the factthat when the surface applied aggregate provides high initial skidresistance using aggregate in the intermix, the surface maintains highskid properties during the entire period of use of the pavement markingsand al so provides increasing skid resistance.

Another unexpected effect of the use of large aggregate intermix withinthe preformed thermoplastic or hot melt applied markers, is the decreaseor essentially complete elimination of tire skid marks on thethermoplastic marking surfaces. Bigger aggregates leading to reductionor elimination of tire tracking was also an unexpected result.

Among additional objectives of the invention include providing arelatively inexpensive pavement marking pattern having two or moresections in which the sections are joined by use of an applied adhesiveand to provide a method for forming a pavement marking pattern whichallows cost efficient factory assembly of the pattern and which preventsdislodging and separation of the pattern sections during handling,transportation and application.

Other objects of the invention are to provide an adhesive which can beconveniently sprayed onto the back of pavement marking patterns whichwill sufficiently adhere thereto and prevent separation of the sectionsduring handling, and not deteriorate the bond between the pavementmarking pattern and the substrate and to provide a method for easyapplication of the adhesively sprayed marking pattern to the substrate.

It should be understood that although examples are given it should notbe construed that these are examples provide the only examples of theinvention and that variations of the present invention are possible,while adhering to the inventive concept herein disclosed.

Incorporation of large grit aggregate into the pavement marking patternallows for manufacturing with decorative markings on the surface of thepreformed thermoplastic sheets that provides excellent anti-skidproperties.

WORKING AND COMPARATIVE EXAMPLES Test Methodology

The surface texture of the preformed thermoplastic is measured using alaser-based Circular Track Meter (CTM) with a vertical resolution of 3microns (μm). The texture is reported in terms of the Mean Profile Depth(MPD) in millimeters. Then the friction of the surface is measured usinga Dynamic Friction Tester (DFT). In the DFT, a disk with three rubbersliders attached to the disk rotates at tangential velocities up to 90km/h then drops onto the surface. The torque generated, as the diskslows once it engages the surface, provides an indication of thefriction at various speeds. The output from the DFT is reported asunitless DFT numbers at various speeds (typically 20, 40, 60 and 80km/h). The DFT and CTM instruments are manufactured by NIPPO Sangyo Co.(Japan). Together, the results from the CTM and DFT are used tocalculate a value known as the International Friction Index (IFI, F60).The IFI can also be estimated by other types of equipment including thewidely used ASTM E274 towed friction trailer test method as well as theBritish pendulum test method and results of different test methods havebeen found to correlate.

Working Example 1

An example of the hydrocarbon resin composition for the preformedthermoplastic of the present invention is provided as follows:

Material composition Escorez 1315-   10% C5 hydrocarbon resin-    5%Refined mineral oil-    2% Escorene EVA MV 02514    3% Fumed silica- 0.5% Titanium dioxide (Rutile)-   10% Glass beads Type 1-   30%Corundum Grit 12   20% CaCO3- 19.5%

The material composition has a softening temperature (Ring and Ball) of118° C. measured according to ASTM D36-06 entitled “Standard Test Methodfor Softening Point of Bitumen (Ring-and-Ball Apparatus)”.

The thermoplastic material composition was extruded using a casting dieto create 125 mil thick preformed thermoplastic sheets. As the sheetswere extruded glass beads were dropped onto the melted thermoplasticmaterial. Subsequently at a location further from the die exit on themanufacturing line, corundum grit 16 was added to the thermoplastic andindented visual heating indicators were applied to the surface.

Using a Flint-2000 propane torch, the material composition was appliedon two square cement boards (20 inches by 20 inches). One of the panelswas tested after application, another was abraded (sand blasted) toexpose the intermix aggregate.

The properties of material tested with DFT and CTM as described aboveare provided in Table 1 below;

TABLE 1 DFT, F60, and MPD Values for Working Example 1 Example 1 DFT20F60 MPD, mm As Applied 0.733 0.425 0.61 After Abrasion 0.853 0.455 0.71

Working Example 2

An example of preformed thermoplastic material based on an alkyd resincomposition is provided as:

Material Composition for Working Example 2 Polyamide resin Uni-Rez 2633 7.2% Modified rosin resin Sylvacote 4981-  6.8% Phthalate plasticizer- 2.8% PE based wax-  2.0% Fumed silica-  0.5% Corundum grit 16   30%TiO2-   10% CaCO3- 40.7%

The material composition softening temperature (R&B) is 124° C.

The material composition was extruded, applied on cement boards, andtested similarly to the Example 1 except that corundum grit 24 wasdropped on the surface during extrusion. The results are provided inTable 2 below:

TABLE 2 DFT, F60, and MPD Values for Working Example 2 Example 2 DFT20F60 MPD, mm As Applied 0.517 0.266 0.463 After Abrasion 0.794 0.379 0.51

Working Example 3

Alkyd type base layer for hot applied formulation Modified rosin resinSylvacote 4981-   8% Modified rosin resin Sylvacote 7021-   9% Castoroil based plasticizer-   3% PE based wax- 2.0% Quartz mix with grit 12to 20 gradation  30% TiO2-  10% CaCO3-  38%

The material composition softening temperature (R&B) is 121° C.

The formulation, after mixing, provided 4-inch wide draw-down plaques.No anti-skid aggregate was applied to the surface of the plaques. Whilestill warm and sufficiently flexible the draw-down plaques were appliedto the cement boards covering the entire 20×20 inch area and creatingsufficient space for testing, using CMT and DFT testers. One of theboards was tested after application and another after abrasion by sandblasting to expose intermix aggregate.

TABLE 3 DFT, F60, and MPD Values for Working Example 3 Example 3 DFT20F60 MPD, mm As Applied 0.15 0.13 0.34 After Abrasion 0.70 0.33 0.46

Working Example 4

An application of preformed thermoplastic insignia using adhesive backedpreformed thermoplastic sheeting was also tested. Pressure sensitiveadhesive (PSA) was applied to the sheets of material made according tothe Example 2 and pre-cut in the shape of AASHTO approved letters. Theletters were applied at the intersection to create a warning “STOP” signusing a READYMARK® tamper. The friction properties of these preformedthermoplastic sheets yielded results similar to the “as applied”properties presented in Example 2.

Working Example 5

A decorative brick pattern was made using colored and patternedthermoplastic sheeting manufactured according to the Example 1 includinga dark red color for bricks and a white color for the grout. Thesections of the patterned thermoplastic sheeting were joined togetherusing EVA based hot melt adhesive. Sheeting was applied to the crosswalkand exhibited properties similar to the “as applied” propertiespresented in Example 1.

Working Example 6

Alkyd based material with blended large aggregate intermix

Material Composition for Working Example 6 Polyamide resin Uni-Rez 2633- 7.5% Modified rosin resin Sylvacote 4981-  6.5% Phthalate plasticizer- 3.2% PE based wax-  1.6% Fumed silica-  0.5% Corundum grit 12    5%Mulcoa 47, gradation 8-20 grit   25% TiO2-   10% CaCO3- 40.7%

Material was processed according to Example 1, with a 90 mil thicknessand corundum grit (or mesh size) 24 was applied during extrusion.

TABLE 4 DFT, F60, and MPD Values for Working Example 4 Example 6 DFT20F60 MPD, mm As Applied 0.47 0.248 0.46 After Abrasion 0.754 0.392 0.51

Comparative Example 1

As an illustration, Comparative Example 1 uses smaller aggregate in theintermix. The preformed thermoplastic was identical to that of WorkingExample 2, except that the Corundum grit 30 was used in the intermix andas a drop on instead of corundum grit 16.

Material Composition for Comparative Example 1 Polyamide resin Uni-Rez2633-  7.2% Modified rosin resin Sylvacote 4981-  6.8% Phthalateplasticizer-  2.8% PE based wax-  2.0% Fumed silica-  0.5% Corundum grit30   30% TiO2-   10% CaCO3- 40.7%

TABLE 5 DFT, F60, and MPD Values for Comparative Example 1 Comp. Example1 DFT20 F60 MPD, mm As Applied 0.42 0.192 0.28 After Abrasion 0.36 0.1720.26

The data shown above, in Table 5 when compared with the previous Tables(1-4) clearly indicates the (heretofore unexpected) improvement over thesmall size corundum after abrasion (wear) for DFT20 (0.70 vs. 0.36) andcalibration friction number F60 (0.35-0.45 vs. 0.17).

1. A method of making a preformed or hot applied thermoplastic markingcomposition comprising a planar top surface portion and a planar bottomsurface portion that are coplanar to each other, wherein said bottomsurface portion is directly applied to a substrate via application ofheat or pressure or both heat and pressure and wherein said top surfaceportion comprises an intermix that exits throughout said thermoplasticcomposition and includes large grit size aggregate in the range of about8 to about 20 mesh or grit size, thereby reducing or eliminating tiretracking while also improving long-term skid resistance.
 2. The methodof making the thermoplastic composition of claim 1, wherein saidaggregate comprises quartz, granite, corundum, calcined clay, metal slagor any combination of said quartz, granite, corundum, calcined clay, ormetal slag.
 3. The method of making the thermoplastic composition ofclaim 1, wherein said thermoplastic marking composition is a sheathing,said sheathing comprising anti-skid resistance materials including saidlarge grit size aggregate with and without retroreflective glass beads,wherein said aggregate and glass beads are either in said intermix ordropped onto said top surface portion before, during, or afterapplication to a substrate.
 4. The method of making the thermoplasticcomposition of claim 1, wherein said thermoplastic sheathing with saidlarge grit size aggregate and with and without retroreflective glassbeads are either in said intermix or dropped onto said top surfaceportion before, during, or after application to a substrate and whereinadditional particles are dropped onto said top surface portion, whereinsaid particles are aggregates, glass beads, including type 1 and type 3glass beads, as well as large grit size aggregate in the range of 8 to20 mesh or grit size said aggregate comprising corundum, crushedgranite, crushed gravel, or quartz, or any combination of said corundum,crushed granite, crushed gravel, and/or quartz.
 5. The method of makingthe thermoplastic composition of claim 1, wherein said large grit sizeaggregate measures greater than 6 on the Mohs Hardness Scale
 6. Themethod of making the thermoplastic composition of claim 1, wherein saidaggregate provides a surface roughness measured using a calibratedfriction number F60, across a yielding values of about 0.17 to about0.40
 7. The method of making the thermoplastic composition of claim 1,wherein said aggregate embedded within the surface of said top surfaceportion provides a surface roughness which is measured as a mean profiledepth and wherein said mean profile depth is between about 0.35 to about0.75 millimeters.
 8. The method of making the thermoplastic compositionof claim 1, wherein said bottom surface portion comprises an adhesivefor bonding said bottom surface portion to any paved surface.
 9. Themethod of making the thermoplastic composition of claim 1, wherein saidtop surface portion includes patterned markings, wherein said patternedmarkings are lines, legends, arrows, indicia, including colored surfacesand sections of said surfaces other than or together with a white color.10. The adhesive of claim 9, wherein said adhesive is sprayable allowingfor bridging said intersection on said planar bottom surfaces of saidgrid section and said insert section forming said unified pavementmarking pattern and wherein said adhesive includes ethylene vinylacetate (EVA) based hot melt or other equivalent hot melt polyamideresins.
 11. The adhesive of claim 10, wherein said adhesive has asoftening point in a range of 90 degrees centigrade to about 210 degreescentigrade and more preferably in a range of 90 degrees centigrade toabout 120 degrees centigrade
 12. The adhesive of claim 9, wherein saidadhesive comprises a thermosetting adhesive.
 13. The adhesive of claim9, wherein said adhesive comprises a thermoplastic adhesive.
 14. Themethod of making thermoplastic composition wherein said thermoplasticcomprises an independent thermoplastic grid section, and an independentthermoplastic insert section, and wherein said insert section resideswithin said grid section and each said insert section is coplanar, andwherein said grid section and said insert section both comprise a planartop surface portion and a planar bottom surface portion that arecoplanar to each other, such that said grid section is in direct contactwith and adjacent to said insert section thereby forming an intersectionbetween said grid section and said insert section, and furthercomprising an adhesive backing layer on said planar bottom surface, saidadhesive backing layer bridging and bonding said planar bottom surfaceto form a unified pavement marking pattern thereby preventing dislodgingor separation of said pavement marking pattern during handling,movement, transportation before application of said pre-bonded pavementmarking to the top of a pavement surface by application of heat orpressure or both heat and pressure, and further comprising large gritsize aggregate in the range of about 8 to about 20 mesh or grit sizethat reduces tire tracking and improves long-term skid resistance. 15.The method of making the thermoplastic composition of claim 14,comprising said grid and a plurality of inserts, each of said insertsseparated by said grid.